The conflict has sparked the biggest emergency stocks release in history in March coordinated by the International Energy Agency.
"Taking into account commitments that have already been fulfilled, we will implement our commitments with a coordinated release through the IEA of 100 million barrels," the G7 said in a joint statement on Friday.
It said it would begin immediately and last four months with a front-loaded substantial diesel release within 20 days by G7 members and partners.
It did not provide a breakdown for the volumes of crude, diesel and other products to be released nor state which countries would participate.
"We will convene in the context of the IEA in the coming days to discuss the possibility of additional diesel releases as necessary," the statement added.
"Europe has just agreed to release a massive amount of their heavily stocked Diesel Oil. The process will begin immediately," Trump wrote in a post on Truth Social on Friday.
The US president is seeking to lower domestic fuel prices ahead of November 3 midterm elections.
The Trump administration had told Germany and France to draw down emergency diesel inventories or face a potential US diesel export ban, Reuters reported on Thursday, citing three people close to the discussions.
The G7 statement said member countries would refrain from imposing export restrictions on energy products between themselves.
"This is a political statement rather than a specific and binding commitment with the large headline number intended to persuade President Trump not to impose a diesel export ban," analysts at Energy Aspects said in a note.
Europe has boosted its imports of US diesel this year due to disrupted supply from Gulf producers due to the Iran war.
EU governments on Friday had discussed a proposal by France for European countries to release 50 million barrels of diesel, and for IEA members to release 50 million barrels of crude oil, three sources familiar with the discussions told Reuters.
A 50-million-barrel release of diesel would equate to approximately 17 per cent of the EU's total emergency stocks of diesel and gasoil, Eurostat data showed, or about three per cent of the bloc's annual consumption.
